Charlene grew up and was educated in Stellenbosch (South Africa), achieving her BSc Food Science degree in 1987 through the University of Stellenbosch. After completing her studies she joined the Council For Scientific and Industrial Research, where she was involved in research for five years and also completed her BSc Hons (Food Science) part time, through the University of Pretoria in 1991. Charlene completed her B Commt (Bachelor of Accounting Science) degree in 2007 through the University of South Africa.

Charlene started her accounting studies whilst working for Roche Pharmaceuticals, a major research & development-based pharmaceutical company and has had roles in Clinical Research and Sales & Marketing. She relocated to the UK in 2007 and is married to Adrian. Charlene joined Exceed UK Ltd as an Accountant Trainee in June 2008, and is responsible for payroll and company secretarial services.

Charlene enjoys calligraphy, travelling and reading and is focused on achieving her ACCA qualification.